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1. Identity statement
Reference TypeJournal Article
Sitemtc-m21d.sid.inpe.br
Holder Codeisadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S
Identifier8JMKD3MGP3W34T/48AKEJP
Repositorysid.inpe.br/mtc-m21d/2023/01.03.16.56   (restricted access)
Last Update2023:01.03.16.56.48 (UTC) simone
Metadata Repositorysid.inpe.br/mtc-m21d/2023/01.03.16.56.48
Metadata Last Update2024:01.02.17.16.38 (UTC) administrator
DOI10.1016/j.mseb.2022.116089
ISSN0921-5107
Citation KeyEscanioAntuTravCora:2023:InSoCa
TitleInfluence of sodium and calcium contaminant in the growth of carbon nanotube on rayon-based carbon fibers
Year2023
MonthJan.
Access Date2024, May 19
Type of Workjournal article
Secondary TypePRE PI
Number of Files1
Size7415 KiB
2. Context
Author1 Escanio, Camila Alves
2 Antunes, Erica Freire
3 Trava-Airoldi, Vladimir Jesus
4 Corat, Evaldo José
Resume Identifier1
2
3
4 8JMKD3MGP5W/3C9JH33
Group1 CMS-ETES-DIPGR-INPE-MCTI-GOV-BR
2 COPDT-CGIP-INPE-MCTI-GOV-BR
3 COPDT-CGIP-INPE-MCTI-GOV-BR
4 COPDT-CGIP-INPE-MCTI-GOV-BR
Affiliation1 Instituto Nacional de Pesquisas Espaciais (INPE)
2 Instituto Nacional de Pesquisas Espaciais (INPE)
3 Instituto Nacional de Pesquisas Espaciais (INPE)
4 Instituto Nacional de Pesquisas Espaciais (INPE)
Author e-Mail Address1 camilaescanio@gmail.com
2 erica.freireantunes@gmail.com
3 vladimirjta@gmail.com
4 evaldo.corat@inpe.br
JournalMaterials Science and Engineering B: Advanced Functional Solid-State Materials
Volume287
Pagese116089
History (UTC)2023-01-03 16:57:13 :: simone -> administrator :: 2023
2024-01-02 17:16:38 :: administrator -> simone :: 2023
3. Content and structure
Is the master or a copy?is the master
Content Stagecompleted
Transferable1
Content TypeExternal Contribution
Version Typepublisher
KeywordsAlkali metals
Catalyst
Rayon
Carbon fiber
Carbon nanotubes
AbstractThis study investigated the role of contaminants commonly found on rayon-based carbon fibers (CF) for the carbon nanotubes (CNT) synthesis. The most common contaminant found on CF is sodium. From the experi-mental results, sodium contaminant indeed performed as a catalyst, but with low efficiency. However, some CF samples also contained calcium as a contaminant, and Ca presence made higher density and better-quality CNT growth. Probably Ca acts as the reducing agent, keeping Na in metallic form along the entire growth process. XPS data suggests a new view of sodium oxide/hydroxide to sodium carbonate transition after CNT synthesis. On CF samples with calcium, sodium keeps activity and carbonate does not form, differently of the sample containing just Na. CF free of contaminants (PAN-based CF) helps set apart the effects and Raman Spectroscopy picked up sodium and calcium effects on the CNT crystalline quality. The sodium presence in rayon-based CF worsens CNT quality when growing from the foreign iron-cobalt catalyst. By another hand, calcium presence helps keeping iron-cobalt nanoparticles surface reduced. Images of Field Emission Gun Scanning Electron Microscopy (FEG-SEM), Energy Dispersive Spectroscopy (EDS), and X-ray Diffraction (XRD) also supported the analysis.
AreaFISMAT
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4. Conditions of access and use
Languageen
Target File1-s2.0-S0921510722004779-main.pdf
User Groupsimone
Reader Groupadministrator
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Visibilityshown
Read Permissiondeny from all and allow from 150.163
Update Permissionnot transferred
5. Allied materials
Next Higher Units8JMKD3MGPCW/3F358GL
8JMKD3MGPCW/46KTFK8
8JMKD3MGPCW/46KUES5
Citing Item Listsid.inpe.br/bibdigital/2022/04.03.23.11 3
sid.inpe.br/mtc-m21/2012/07.13.14.45.37 1
sid.inpe.br/bibdigital/2022/04.03.17.52 1
DisseminationWEBSCI; PORTALCAPES; SCOPUS.
Host Collectionurlib.net/www/2021/06.04.03.40
6. Notes
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